Kajian Eksperimental Pengaruh Variasi Discharge Rate terhadap Karakteristik Elektrokimia dan Termal Baterai Lithium-Ion Silinder LCO, LFP, NMC, dan NCA

Authors

  • Sumedi Sumedi Institut Teknologi Perusahaan Listrik Negara
  • Ignatius Rendroyoko Institut Teknologi Perusahaan Listrik Negara
  • Prasetyo Adi Nugroho Institut Teknologi Perusahaan Listrik Negara

DOI:

https://doi.org/10.55606/juprit.v5i3.6753

Keywords:

Discharge Rate, Electrochemical Characteristics, Lithium-Ion Battery, Simple Additive Weighting, Thermal Response

Abstract

Lithium-ion batteries are a key component of modern energy storage systems, including electric vehicles and renewable energy integration. Nevertheless, their performance is strongly affected by operating conditions, especially the discharge rate. This study aims to evaluate the effect of discharge rate variation (0.5C, 1C, 2C, and 3C) on the electrochemical and thermal characteristics of four commercial cylindrical lithium-ion cell chemistries - LCO, LFP, NMC, and NCA, using a quantitative experimental method with a Neware CE-6002n Battery Testing System and a Hioki LR8450 Memory HiLogger. Test results show that discharge capacity decreased by 2.3–8.9% from 0.5C to 3C, while discharge energy decreased significantly by 14–21% due to reduced working voltage caused by internal resistance. Energy efficiency dropped from a range of 83–94% to 65–80%. Surface temperatures of the NMC and NCA cells exceeded 60°C at a 3C discharge rate, surpassing the safe operating limit, whereas LCO exhibited the lowest ΔT value. Based on the Simple Additive Weighting method applied to seven performance parameters, the overall performance ranking obtained was NMC > LCO > NCA > LFP. The quadratic regression model provided the best representation for capacity, energy, and temperature rise, while the geometric model was most suitable for energy efficiency.

Downloads

Download data is not yet available.

References

Alldatasheet. (n.d.). ICR18650-26J datasheet. Samsung SDI. Retrieved May 2, 2026, from https://www.alldatasheet.com/datasheet-pdf/download/1492276/SAMSUNG/ICR18650-26J.html

Andrenacci, N., Pasquali, M., Vellucci, F., & Venanzoni, A. (2024). Estimation procedure for the degradation of a lithium-ion battery pack. Batteries, 10(7), Article 234. https://doi.org/10.3390/batteries10070234

Barcellona, S., & Piegari, L. (2020). Effect of current on cycle aging of lithium ion batteries. Journal of Energy Storage, 29, Article 101310. https://doi.org/10.1016/j.est.2020.101310

Bašić, H., Bobanac, V., & Pandžić, H. (2023). Determination of lithium-ion battery capacity for practical applications. Batteries, 9(9), Article 459. https://doi.org/10.3390/batteries9090459

Beard, K. W. (Ed.). (2019). Linden’s handbook of batteries (5th ed.). McGraw-Hill Education.

Chen, H. Y., & Chen, C. (2022). Evaluation of calibration equations by using regression analysis: An example of chemical analysis. Sensors, 22(2), Article 447. https://doi.org/10.3390/s22020447

Chicco, D., Warrens, M. J., & Jurman, G. (2021). The coefficient of determination R-squared is more informative than SMAPE, MAE, MAPE, MSE, and RMSE in regression analysis evaluation. PeerJ Computer Science, 7, Article e623. https://doi.org/10.7717/peerj-cs.623

Evro, S., Ajumobi, A., Mayon, D., & Tomomewo, O. S. (2024). Navigating battery choices: A comparative study of lithium iron phosphate and nickel manganese cobalt battery technologies. Future Batteries, 4, Article 100007. https://doi.org/10.1016/j.fub.2024.100007

Heenan, T. M. M., et al. (2020). An advanced microstructural and electrochemical datasheet on 18650 Li-ion batteries with nickel-rich NMC811 cathodes and graphite-silicon anodes. Journal of the Electrochemical Society, 167(14), Article 140530. https://doi.org/10.1149/1945-7111/abc4c1

Hioki E.E. Corporation. (2018). GENNECT One user's manual (Rev. 22).

International Electrotechnical Commission. (2017). IEC 61960-3:2017: Secondary cells and batteries containing alkaline or other non-acid electrolytes—Part 3: Prismatic and cylindrical lithium secondary cells and batteries made from them. IEC.

International Energy Agency. (2025). Global EV outlook 2025: Expanding sales in diverse markets. IEA.

Jeon, M., Lee, E., Park, H., Yoon, H., & Keel, S. (2022). Effect of thermal abuse conditions on thermal runaway of NCA 18650 cylindrical lithium-ion battery. Batteries, 8(10), Article 196. https://doi.org/10.3390/batteries8100196

Jones, C. M., Sudarshan, M., García, R. E., & Tomar, V. (2023). Direct measurement of internal temperatures of commercially-available 18650 lithium-ion batteries. Scientific Reports, 13(1), Article 14580. https://doi.org/10.1038/s41598-023-41718-w

Kuntz, P., et al. (2021). Identification of degradation mechanisms by post-mortem analysis for high power and high energy commercial Li-ion cells after electric vehicle aging. Batteries, 7(3), Article 48. https://doi.org/10.3390/batteries7030048

Li, X., et al. (2019). Degradation mechanisms of high capacity 18650 cells containing Si-graphite anode and nickel-rich NMC cathode. Electrochimica Acta, 297, 1109–1120. https://doi.org/10.1016/j.electacta.2018.11.194

Liu, Y., Zhang, L., Huang, X., Hao, M., & Huang, X. (2024). Laser-induced thermal runaway dynamics of cylindrical lithium-ion battery. Journal of Energy Storage, 86, Article 111337. https://doi.org/10.1016/j.est.2024.111337

Madani, S. S., Schaltz, E., & Kær, S. K. (2019). Effect of current rate and prior cycling on the coulombic efficiency of a lithium-ion battery. Batteries, 5(3), Article 57. https://doi.org/10.3390/batteries5030057

Mekdour, K., Reddy, A. K. M. R., Dawkins, J. I. G., Selva, T. M. G., & Zaghib, K. (2025). Comparative analysis of cell design: Form factor and electrode architectures in advanced lithium-ion batteries. Batteries, 11(12), Article 450. https://doi.org/10.3390/batteries11120450

Nebl, C., Steger, F., & Schweiger, H. G. (2017). Discharge capacity of energy storages as a function of the discharge current—Expanding Peukert's equation. International Journal of Electrochemical Science, 12(6), 4940–4957. https://doi.org/10.20964/2017.06.51

Neware Technology Ltd. (n.d.). Specifications CE-6000 series battery testing system. https://www.neware.com.cn

Parschau, A., Degler, D., Fill, A., Birke, K. P., & Allmendinger, F. (2023). Cycle tests on the influence of different charging currents—A case study on different commercial, cylindrical lithium-ion cells. Batteries, 9(2), Article 83. https://doi.org/10.3390/batteries9020083

Popović, O., Rupar, V., Praštalo, Ž., Aleksandrović, S., & Milisavljević, V. (2024). Testing of NMC and LFP Li-ion cells for surface temperature at various conditions. Case Studies in Thermal Engineering, 61, Article 104930. https://doi.org/10.1016/j.csite.2024.104930

Qu, J. G., Jiang, Z. Y., & Zhang, J. F. (2022). Investigation on lithium-ion battery degradation induced by combined effect of current rate and operating temperature during fast charging. Journal of Energy Storage, 52, Article 104811. https://doi.org/10.1016/j.est.2022.104811

Samsung SDI. (2015). Specification of product for lithium-ion rechargeable cell, model: INR18650-35E.

Schmitt, J., Rehm, M., Karger, A., & Jossen, A. (2023). Capacity and degradation mode estimation for lithium-ion batteries based on partial charging curves at different current rates. Journal of Energy Storage, 59, Article 106517. https://doi.org/10.1016/j.est.2022.106517

Tran, M. K., Dacosta, A., Mevawalla, A., Panchal, S., & Fowler, M. (2021). Comparative study of equivalent circuit models performance in four common lithium-ion batteries: LFP, NMC, LMO, NCA. Batteries, 7(3), Article 51. https://doi.org/10.3390/batteries7030051

Vafaei, N., Ribeiro, R. A., & Camarinha-Matos, L. M. (2022). Assessing normalization techniques for simple additive weighting method. Procedia Computer Science, 199, 1229–1236. https://doi.org/10.1016/j.procs.2022.01.156

Voltt. (n.d.). LG Chem INR18650-MJ1 lithium-ion battery cell datasheet and models. https://voltt.aboutenergy.io/cell-library/LG-Chem_INR18650-MJ1

Wang, X., Chen, Y., Chen, L., Liu, S., Zhu, Y., & Deng, Y. (2024). The impact of wide discharge C-rates on the voltage plateau performance of cylindrical ternary lithium-ion batteries. Energies, 17(14), Article 3488. https://doi.org/10.3390/en17143488

Wintonic. (n.d.). IFR26650 3500mAh 3.2V—Product specification. Retrieved May 2, 2026, from https://wintonic.com/en/product-44282-53344-183100.html

Downloads

Published

2026-08-31

How to Cite

Sumedi Sumedi, Ignatius Rendroyoko, & Prasetyo Adi Nugroho. (2026). Kajian Eksperimental Pengaruh Variasi Discharge Rate terhadap Karakteristik Elektrokimia dan Termal Baterai Lithium-Ion Silinder LCO, LFP, NMC, dan NCA. Jurnal Penelitian Rumpun Ilmu Teknik, 5(3), 90–107. https://doi.org/10.55606/juprit.v5i3.6753